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This is one of the best solutions I have seen so far without using plugins

MagePal/CustomButton/view/adminhtml/layout/adminhtml_sales_order_view.xml

<?xml version="1.0"?>
<page xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" xsi:noNamespaceSchemaLocation="urn:magento:framework:View/Layout/etc/page_configuration.xsd">
    <body>
        <referenceBlock name="sales_order_edit">
            <block class="MagePal\CustomButton\Block\Adminhtml\Order\View\Buttons" name="custom_buttons">
                <action method="addButtons"/>
            </block>
        </referenceBlock>
    </body>
</page>

MagePal/CustomButton/Block/Adminhtml/Order/View/Buttons.php

namespace MagePal\CustomButton\Block\Adminhtml\Order\View;

class Buttons extends \Magento\Sales\Block\Adminhtml\Order\View
{    
    public function __construct(
        \Magento\Backend\Block\Widget\Context $context,
        \Magento\Framework\Registry $registry,
        \Magento\Sales\Model\Config $salesConfig,
        \Magento\Sales\Helper\Reorder $reorderHelper,
        array $data = []
    ) {
        parent::__construct($context, $registry, $salesConfig, $reorderHelper, $data);
    }

    public function addButtons()
    {
        $parentBlock = $this->getParentBlock();
        $buttonUrl = $this->_urlBuilder->getUrl(
            'adminhtml/custombutton/new',
            ['order_id' => $parentBlock->getOrderId()]
        );

        $this->getToolbar()->addChild(
              'create_custom_button',
              \Magento\Backend\Block\Widget\Button::class,
              ['label' => __('Custom Button'), 'onclick' => 'setLocation(\'' . $buttonUrl . '\')']
            );
        }
        return $this;
    }

}