K.c you can do this by Layout xml changes.
and you need change it Layout 1column.phtml
.
<action method="setTemplate"><template>page/1column.phtml</template></action>
See at http://www.amitbera.com/how-to-change-page-layout-in-magento/
<CATEGORY_YOUCATID> page/1column.phtml <CATEGORY_YOUCATID>
Example:guess that your category id
is 10
.If you want to assign 1column
desing then you need
to put below code local.xml at app/design/frontent/ your package/your template/layout/
<CATEGORY_10>
<reference name="root">
<action method="setTemplate"><template>page/1column.phtml</template></action>
</reference>
<CATEGORY_10>