Yep it's possible, create two Customer tax class under **Sales->Tax->Manage Customer Tax Classes** Let's call them **Retail Customer** and **Trade Customer** Now Add Tax Rates under **Sales->Tax->Manage Tax Rates**, provide 0.00 for let's call them **Tax Standard** and **Tax Zero** Now add Tax rules under **Sales->Tax->Manage Tax Rules** **Tax Standard** and **Tax Zero** You can then specify Tax Zero to be used with custom group Trade and Tax Standard to be used with retail. You'll adjust general tax settings under **System->configuration->Sales->Tax** Screenshot attached for reference. [![enter image description here][1]][1] [1]: https://i.sstatic.net/cewHY.jpg