Add column payment in order to magento administrator 1.9.1.
I would add a column stating what was the form of customer payment in the admin panel.
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Basically For the Sales Order grid Customization you can use here some links from external resources. But for that You Should Have to Basic Knowledge of Module/extension Development.
these are some free extension for u... http://www.magentocommerce.com/magento-connect/enhanced-admin-grids-editor.html http://www.magentocommerce.com/magento-connect/custom-order-grid-1.html
this is some resource of admin order grid customization..