Is it possible to send two order emails with different email templates?
If yes please let me know how we can solve this ?
or let me know if any extension will achieve this goal
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Rewrite Mage_Sales_Model_Order module to add your custom logic to sendNewOrderEmail() You could disable order emails (see Magento: send New Order Email only with cronjobs) create (eg checkout_submit_all_after) and do your own custom email sending