Example using CURL:
$url = 'https://example.org/connector.php';
$postData = array();
$postData['var2'] = join(',', $emails);
$postData['var3'] = 'amasty';
$ch = curl_init();
curl_setopt($ch, CURLOPT_URL, $url);
curl_setopt($ch, CURLOPT_RETURNTRANSFER, 1);
curl_setopt($ch, CURLOPT_POST, 1);
curl_setopt($ch, CURLOPT_POSTFIELDS, $postData);
curl_setopt($ch, CURLOPT_FOLLOWLOCATION, 1);
curl_setopt($ch, CURLOPT_HEADER, 0);
$result = curl_exec($ch);
curl_close($ch);
if (strlen($result) > 2){
//do something
}
edit
You can use this code in admin controller created by this tutorial http://www.magentocommerce.com/wiki/5_-_modules_and_development/0_-_module_development_in_magento/custom_module_with_custom_database_table