I have a Magento 1.9 and it does not show the button to print order pdf in orders. How I can enable this?
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AFAIK the Print button is only available when viewing a shipment, an invoice or a credit memo out of the box in Magento 1.9.
I suggest you follow this StackOverflow answer to add a Print button to your order view page: https://stackoverflow.com/questions/14513085/order-view-page-print-pdf-button-magento