I try to export my whole products, i get 500 Internal Server Error during only product export.
Export Error :
Note : When i try to export minimum of products like 100's of products, my export working and bulk export only not working.
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Since Magento is not able to catch and handle this error, it means the error is from server issue.
You need to check server error logs to know more:
Please let me know if you have any question.
A 500 error output isn't really enough information to help you diagnose a problem like this. You need to check your server logs to get a more accurate account of what is actually going wrong.
That said, given that the export is working in small volumes but not larger ones its likely that your reaching a resource limit. At a guess I would say phps memory limit. Again you would need to check your logs to confirm this.