LuFFy's answer is technically incorrect as it has 3 issues:
- it will remove values for
admin
store view only leaving some store-views related garbage
- it will remove unused values of attributes of all entity types
- it will remove ALL values from attributes with "multiple select" type regardless if they are assigned to any products or not because they options are stored in
catalog_product_entity_varchar
and not catalog_product_entity_int
The query below addresses these problems:
DELETE o, v
FROM `eav_attribute` a
INNER JOIN `eav_attribute_option` o ON a.`attribute_id` = o.`attribute_id`
INNER JOIN `eav_attribute_option_value` v ON v.`option_id` = o.`option_id`
INNER JOIN `eav_entity_type` t ON t.`entity_type_id` = a.`entity_type_id`
LEFT JOIN `catalog_product_entity_int` pi ON o.`option_id` = pi.`value` AND o.`attribute_id` = pi.`attribute_id`
LEFT JOIN `catalog_product_entity_varchar` pv ON o.`option_id` = pv.`value` AND o.`attribute_id` = pv.`attribute_id`
WHERE pi.`entity_id` IS NULL
AND pv.`entity_id` IS NULL
AND t.`entity_type_code` = "catalog_product"