Default report is available in report -> sales -> coupons.
And with script you can find used coupan count and customer details very easily :
$coupon = Mage::getModel('salesrule/coupon/usage');
$coupon->load('coupan_id''code', 'code''coupon_id');
if($coupon->getId()) {
$timesUsed = $coupon->getTimesUsed();
$customer = $coupon->getCustomerId();
echo $timesUsed;
echo $customer;
}